Which scientific principle predicts that the solubility of a gas or volatile substance in a liquid is proportional to the partial pressure of the substance over the liquid (P = kC)?

Correct Answer: C

Rationale: Henry's Law states that the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid. The equation P = kC represents Henry's Law, where P is the partial pressure of the gas, C is the concentration of the gas in the liquid, and k is a constant. This law is applicable to dilute solutions where the gas does not significantly affect the liquid's volume. Therefore, in the context of gas solubility in liquids, Henry's Law is the appropriate principle that describes the relationship between solubility and partial pressure. Boyle's Law relates the pressure and volume of a gas at constant temperature, Gay-Lussac's Law deals with the pressure and temperature relationship of a gas at constant volume, and Charles' Law describes the relationship between the volume and temperature of a gas at constant pressure. These laws are not directly related to the solubility of gases in liquids, making them incorrect choices for this question.

Correct Answer: A

Rationale: Statement A is correct. pH is a measure of the effective concentration of hydrogen ions in a solution, and it is related to the molarity of H+ by the formula pH = - log [H+]. This equation illustrates the logarithmic relationship between pH and the concentration of hydrogen ions. Oxygen ions and hydrogen atoms are not directly related to pH in the same manner as hydrogen ions. Acidity is determined by the concentration of hydrogen ions in a solution, and this concentration is what pH measures. Therefore, option A is the only statement that correctly defines the relationship between pH and the concentration of hydrogen ions in a solution. Choices B, C, and D are incorrect as they provide inaccurate information about the relationship between pH and the ions/atoms mentioned. Option B incorrectly associates pH with oxygen ions, option C mentions hydrogen atoms instead of hydrogen ions, and option D confuses acidity with pH, which is a measure of hydrogen ion concentration, not molarity.

Correct Answer: B

Rationale: The correct answer is B. The factors that influence rates of reaction are temperature, particle size, concentration, and the presence of a catalyst. Temperature affects the speed of molecules, particle size impacts the available surface area for reactions, concentration influences the collision frequency between reactant molecules, and catalysts accelerate reactions by providing an alternative pathway with lower activation energy. Choices A, C, and D are incorrect as they either include irrelevant factors that do not affect reaction rates (barometric pressure, container material, elevation, and volatility) or lack important factors that do influence reaction rates (like a catalyst).

Correct Answer: A

Rationale: A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate. This is because a higher concentration means there are more reactant molecules in a given volume, increasing the likelihood of collisions between them. With more collisions occurring, there is a greater chance of successful collisions leading to the formation of products, hence increasing the reaction rate. Choice B is incorrect as a lower concentration decreases the number of collisions, reducing the reaction rate. Choice C is incorrect as a higher concentration increases collision frequency, which typically results in a higher reaction rate. Choice D is incorrect as a higher concentration usually leads to more collisions, thus increasing the reaction rate.

Correct Answer: B

Rationale: The correct answer is B, Dalton's law. Dalton's law states that in a mixture of non-reacting gases, the total pressure is equal to the sum of the partial pressures of the individual gases. The equation Ptot = Pa + Pb represents Dalton's law, where Ptot is the total pressure, and Pa and Pb are the component pressures. Choice A, Henry's law, deals with the solubility of gases in liquids. Choice C, Boyle's law, describes the inverse relationship between the pressure and volume of a gas at constant temperature. Choice D, Gay-Lussac's law, states that the pressure of a gas is directly proportional to its absolute temperature when volume is constant.