HESI A24
HESI A2 Chemistry Practice Test Questions
Question 1 of 5
Under which of the following conditions do real gases approach ideal behavior?
Correct Answer: A
Rationale: Real gases approach ideal behavior at high pressure and high temperature. At these conditions, the volume of the gas molecules becomes negligible compared to the total volume of the gas. Additionally, the average distance between molecules becomes small enough for intermolecular forces to become less significant, leading to behavior that closely mirrors the assumptions of the ideal gas law. Choice B is incorrect because low pressure does not favor ideal behavior as the volume of gas molecules becomes more significant. Choice C is incorrect as the boiling point of water does not directly relate to ideal gas behavior. Choice D is incorrect because real gases can approach ideal behavior under specific conditions, such as high pressure and high temperature.
Question 2 of 5
Which law is expressed by the equation: Ptot = Pa + Pb, where P represents pressure, Ptot is the total pressure, and Pa and Pb are component pressures?
Correct Answer: B
Rationale: The correct answer is B, Dalton's law. Dalton's law states that in a mixture of non-reacting gases, the total pressure is equal to the sum of the partial pressures of the individual gases. The equation Ptot = Pa + Pb represents Dalton's law, where Ptot is the total pressure, and Pa and Pb are the component pressures. Choice A, Henry's law, deals with the solubility of gases in liquids. Choice C, Boyle's law, describes the inverse relationship between the pressure and volume of a gas at constant temperature. Choice D, Gay-Lussac's law, states that the pressure of a gas is directly proportional to its absolute temperature when volume is constant.
Question 3 of 5
Which, if any, of these statements about solubility is correct?
Correct Answer: D
Rationale: A. The solubility of a substance is indeed defined as the concentration of a solute that can be dissolved in a solvent to form a saturated solution at a specific temperature and pressure. B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble because they do not dissolve in significant amounts in the solvent. C. A saturated solution is one that cannot dissolve any more solute as it has reached its maximum capacity at a specific temperature and pressure. Therefore, all the statements provided are correct, making option D the correct answer.
Question 4 of 5
One factor that affects rates of reaction is concentration. Which of these statements about concentration is/are correct?
Correct Answer: A
Rationale: A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate. This is because a higher concentration means there are more reactant molecules in a given volume, increasing the likelihood of collisions between them. With more collisions occurring, there is a greater chance of successful collisions leading to the formation of products, hence increasing the reaction rate. Choice B is incorrect as a lower concentration decreases the number of collisions, reducing the reaction rate. Choice C is incorrect as a higher concentration increases collision frequency, which typically results in a higher reaction rate. Choice D is incorrect as a higher concentration usually leads to more collisions, thus increasing the reaction rate.
Question 5 of 5
Bonds involve electrons that are not equally shared, and may be deemed as an intermediate between the extremes represented by and bonds.
Correct Answer: C
Rationale: Chemical bonds involve electrons that are not equally shared, and may be deemed as an intermediate between the extremes represented by covalent and ionic bonds. This is the most accurate statement among the choices as it correctly describes the nature of chemical bonds, highlighting their intermediate position between covalent bonds (where electrons are shared) and ionic bonds (where electrons are transferred). 'Ionic bonds' (choice A) are not the correct answer because they represent a type of chemical bond where electrons are transferred, not shared. 'Covalent bonds' (choice B) are not the correct answer either because they represent a type of chemical bond where electrons are shared equally. 'Polar bonds' (choice D) are not the correct answer as they involve an unequal sharing of electrons but do not represent the intermediate position between covalent and ionic bonds as chemical bonds do. Therefore, the correct answer is 'Chemical bonds.'
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