Correct Answer: B

Rationale: The triple point is a unique temperature and pressure where all three phases (solid, liquid, and gas) of a pure substance can coexist in equilibrium. It is a constant for each substance and independent of container size. Choice A is incorrect because the triple point is a fixed point regardless of the container size. Choice C is incorrect as the pressure at the triple point is specific for each substance and will not be zero unless the substance has unique properties. Choice D is incorrect since the temperature at the triple point is precisely defined and cannot be above the boiling point of the liquid phase.

Correct Answer: A

Rationale: A refrigerator operates on a Carnot cycle by transferring heat from a cold reservoir to a hot reservoir. Choice A is correct because a refrigerator removes heat from a cold reservoir at a lower temperature. Choice B is incorrect as a refrigerator does not violate the first law of thermodynamics but rather requires work input to transfer heat. Choice C is incorrect as a refrigerator does not increase the total entropy of the universe. Choice D is incorrect because a refrigerator does not operate isothermally at both the hot and cold reservoirs.

Correct Answer: C

Rationale: The boundary layer effect occurs when a thin layer of fluid near the surface of a solid adheres to it due to viscosity. This layer experiences a velocity gradient as the fluid farther from the surface moves faster, while the fluid closest to the surface is nearly stationary.

Correct Answer: D

Rationale: The Clausius inequality states that for a cyclic process involving heat transfer at a single constant temperature, the integral of heat transfer divided by temperature (∫ dQ/T) must be less than or equal to zero. This inequality reflects the irreversibility of natural processes. Choice A is incorrect as there is a direct relationship between heat transfer and temperature in the Clausius inequality. Choice B is incorrect because the integral of dQ/T must be less than or equal to zero, not greater than or equal to zero. Choice C is incorrect because the integral of Q/T is not a constant in a cyclic process involving heat transfer at a single constant temperature.

Correct Answer: A

Rationale: Distance is a scalar quantity because it has only magnitude and no direction. It is simply the total length of the path travelled by an object. Scalars are quantities that are fully described by their magnitude alone, without any reference to direction. Velocity and acceleration are vector quantities as they have both magnitude and direction. Displacement is also a vector quantity as it is the change in position of an object and includes both magnitude and direction.