The first law of thermodynamics is a principle of energy conservation. It states that:

Correct Answer: C

Rationale: The first law of thermodynamics states that energy cannot be created or destroyed; it can only be transferred or converted from one form to another, ensuring energy conservation in any system. Choice A is incorrect because it goes against the principle of energy conservation. Choice B is incorrect as it refers to the second law of thermodynamics, which states that the total entropy of an isolated system always increases. Choice D is incorrect because the temperature of a system is not directly proportional to its entropy.

Correct Answer: C

Rationale: The correct answer is C: "They have the same temperature." The zeroth law of thermodynamics states that if two systems are each in thermal equilibrium with a third system, they are also in thermal equilibrium with each other. This implies that they have the same temperature. Choice A is incorrect because pressure is not the determining factor for thermal equilibrium. Choice B is incorrect because volume alone does not dictate thermal equilibrium. Choice D is incorrect as the materials the systems are made of do not determine thermal equilibrium according to the zeroth law of thermodynamics.

Correct Answer: A

Rationale: A refrigerator operates on a Carnot cycle by transferring heat from a cold reservoir to a hot reservoir. Choice A is correct because a refrigerator removes heat from a cold reservoir at a lower temperature. Choice B is incorrect as a refrigerator does not violate the first law of thermodynamics but rather requires work input to transfer heat. Choice C is incorrect as a refrigerator does not increase the total entropy of the universe. Choice D is incorrect because a refrigerator does not operate isothermally at both the hot and cold reservoirs.

Correct Answer: D

Rationale: The Clausius inequality states that for a cyclic process involving heat transfer at a single constant temperature, the integral of heat transfer divided by temperature (∫ dQ/T) must be less than or equal to zero. This inequality reflects the irreversibility of natural processes. Choice A is incorrect as there is a direct relationship between heat transfer and temperature in the Clausius inequality. Choice B is incorrect because the integral of dQ/T must be less than or equal to zero, not greater than or equal to zero. Choice C is incorrect because the integral of Q/T is not a constant in a cyclic process involving heat transfer at a single constant temperature.

Correct Answer: B

Rationale: The triple point is a unique temperature and pressure where all three phases (solid, liquid, and gas) of a pure substance can coexist in equilibrium. It is a constant for each substance and independent of container size. Choice A is incorrect because the triple point is a fixed point regardless of the container size. Choice C is incorrect as the pressure at the triple point is specific for each substance and will not be zero unless the substance has unique properties. Choice D is incorrect since the temperature at the triple point is precisely defined and cannot be above the boiling point of the liquid phase.