HESI A2
HESI A2 Chemistry Practice Test Questions
Question 1 of 5
Bonds involve electrons that are not equally shared, and may be deemed as an intermediate between the extremes represented by and bonds.
Correct Answer: C
Rationale: Chemical bonds involve electrons that are not equally shared, and may be deemed as an intermediate between the extremes represented by covalent and ionic bonds. This is the most accurate statement among the choices as it correctly describes the nature of chemical bonds, highlighting their intermediate position between covalent bonds (where electrons are shared) and ionic bonds (where electrons are transferred). 'Ionic bonds' (choice A) are not the correct answer because they represent a type of chemical bond where electrons are transferred, not shared. 'Covalent bonds' (choice B) are not the correct answer either because they represent a type of chemical bond where electrons are shared equally. 'Polar bonds' (choice D) are not the correct answer as they involve an unequal sharing of electrons but do not represent the intermediate position between covalent and ionic bonds as chemical bonds do. Therefore, the correct answer is 'Chemical bonds.'
Question 2 of 5
Which scientific principle predicts that the solubility of a gas or volatile substance in a liquid is proportional to the partial pressure of the substance over the liquid (P = kC)?
Correct Answer: C
Rationale: Henry's Law states that the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid. The equation P = kC represents Henry's Law, where P is the partial pressure of the gas, C is the concentration of the gas in the liquid, and k is a constant. This law is applicable to dilute solutions where the gas does not significantly affect the liquid's volume. Therefore, in the context of gas solubility in liquids, Henry's Law is the appropriate principle that describes the relationship between solubility and partial pressure. Boyle's Law relates the pressure and volume of a gas at constant temperature, Gay-Lussac's Law deals with the pressure and temperature relationship of a gas at constant volume, and Charles' Law describes the relationship between the volume and temperature of a gas at constant pressure. These laws are not directly related to the solubility of gases in liquids, making them incorrect choices for this question.
Question 3 of 5
Which law states that the pressure of an ideal gas is inversely proportional to its volume, given that the temperature and amount of gas remain constant?
Correct Answer: D
Rationale: Boyle's law describes the relationship between the pressure and volume of an ideal gas when the temperature and amount of gas are constant. According to Boyle's law, if the pressure of a gas increases, its volume decreases proportionally, and vice versa. This law is expressed by the equation P1V1 = P2V2, where P1 and V1 represent the initial pressure and volume, while P2 and V2 represent the final pressure and volume when the temperature and amount of gas remain unchanged. Understanding Boyle's law is essential in comprehending the behavior of gases under varying conditions and is fundamental in the study of thermodynamics. The other choices are incorrect: - Henry's law deals with the solubility of gases in liquids, not the relationship between pressure and volume of gases. - Dalton's law states that the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of individual gases, not the pressure-volume relationship. - Brown's law is a fabricated concept and does not exist in the context of gas laws.
Question 4 of 5
Which of the following statements, if any, are correct?
Correct Answer: A
Rationale: Statement A is correct. pH is a measure of the effective concentration of hydrogen ions in a solution, and it is related to the molarity of H+ by the formula pH = - log [H+]. This equation illustrates the logarithmic relationship between pH and the concentration of hydrogen ions. Oxygen ions and hydrogen atoms are not directly related to pH in the same manner as hydrogen ions. Acidity is determined by the concentration of hydrogen ions in a solution, and this concentration is what pH measures. Therefore, option A is the only statement that correctly defines the relationship between pH and the concentration of hydrogen ions in a solution. Choices B, C, and D are incorrect as they provide inaccurate information about the relationship between pH and the ions/atoms mentioned. Option B incorrectly associates pH with oxygen ions, option C mentions hydrogen atoms instead of hydrogen ions, and option D confuses acidity with pH, which is a measure of hydrogen ion concentration, not molarity.
Question 5 of 5
Which of the following lists four factors that affect rates of reaction?
Correct Answer: B
Rationale: The correct answer is B. The factors that influence rates of reaction are temperature, particle size, concentration, and the presence of a catalyst. Temperature affects the speed of molecules, particle size impacts the available surface area for reactions, concentration influences the collision frequency between reactant molecules, and catalysts accelerate reactions by providing an alternative pathway with lower activation energy. Choices A, C, and D are incorrect as they either include irrelevant factors that do not affect reaction rates (barometric pressure, container material, elevation, and volatility) or lack important factors that do influence reaction rates (like a catalyst).