HESI A2
Chemistry Hesi A2 Questions
Question 1 of 9
Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?
Correct Answer: C
Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.
Question 2 of 9
To the nearest whole number, what is the mass of one mole of hydrogen chloride?
Correct Answer: C
Rationale: The molar mass of hydrogen chloride (HCl) is calculated by adding the atomic masses of hydrogen (H) and chlorine (Cl) together. The atomic mass of hydrogen is approximately 1 g/mol, and the atomic mass of chlorine is approximately 35.5 g/mol. Therefore, the molar mass of hydrogen chloride (HCl) is approximately 1 + 35.5 = 36.5 g/mol. When rounded to the nearest whole number, it is 36 g/mol. Therefore, the correct answer is 36 g/mol. Choices A, B, and D are incorrect as they do not reflect the accurate molar mass of hydrogen chloride.
Question 3 of 9
In the solid state, you would expect a nonmetal to be _________.
Correct Answer: A
Rationale: In the solid state, you would expect a nonmetal to be brittle. Nonmetals generally lack the malleability and ductility of metals, which makes them prone to being brittle and easily fractured under stress. This property is due to the lack of metallic bonding in nonmetals, which results in a more rigid and less flexible structure. Choice B, 'lustrous,' is incorrect because nonmetals typically do not exhibit a shiny or reflective surface like metals do. Choice C, 'malleable,' is also incorrect as nonmetals lack the ability to be hammered or rolled into thin sheets like metals. Choice D, 'conductive,' is incorrect since nonmetals are generally poor conductors of electricity compared to metals.
Question 4 of 9
What are the products of combustion of a hydrocarbon in excess oxygen?
Correct Answer: A
Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.
Question 5 of 9
Why does fluorine have a higher ionization energy than oxygen?
Correct Answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
Question 6 of 9
If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
Correct Answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
Question 7 of 9
Which substance shows a decrease in solubility in water with an increase in temperature?
Correct Answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
Question 8 of 9
The molar mass of some gases is as follows: carbon monoxide-28.01 g/mol; helium-4.00 g/mol; nitrogen-28.01 g/mol; and oxygen-32.00 g/mol. Which would you expect to diffuse most rapidly?
Correct Answer: B
Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.
Question 9 of 9
A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?
Correct Answer: C
Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.